List of CAU-MOFs

 

MOF

Formula

Publication

CAU-1

[Al6(OH)6(OCH3)12(BDC-NH2)]

T. Ahnfeldt, N. Guillou, D. Gunzelmann, I. Margiolaki,
T. Loiseau, G. Férey, J. Senker, N. Stock
 

[Al4(OH)2(OCH3)4(H2N-bdc)3]·xH2O: A 12-Connected Porous Metal–Organic Framework with an Unprecedented Aluminum-Containing Brick
 

Angew. Chem., 2009, 121, 5265-5268.

CAU-2

[Mg2(H2O)2(O3PCH2-NC4H8N-CH2PO3)]

M. T. Wharmby, G. M. Pearce, J. P.S. Mowat, J. M. Griffin, S. E. Ashbrook, P. A. Wright, L.-H. Schilling, A. Lieb,
N. Stock, S. Chavan, S. Bordiga, E. Garcia,
G. D. Pirngruber, M. Vreeke and L. Gora

Synthesis and crystal chemistry of the STA-12 family of metal N,N′-piperazinebis(methylenephosphonate)s and applications of STA-12(Ni) in the separation of gases
 

Micropor. Mesopor. Mater., 2012, 157, 3-17.

CAU-3

[Al2(OCH3)4(O2C-X-CO2)]

H. Reinsch, M. Feyand, T. Ahnfeldt and N. Stock
 

CAU-3: A new family of porous MOFs with a novel
Al-based brick: [Al2(OCH3)4(O2C-X-CO2)] (X = aryl)
 

Dalton Trans., 2012, 41, 4164-4171.

CAU-4

[Al(BTB)]

H. Reinsch, M. Krüger, J. Wack, J. Senker, F. Salles, G. Maurin, N. Stock
 

A new aluminium-based microporous metal-organic framework: Al(BTB) (BTB = 1,3,5-benzenetrisbenzoate)
 

Micropor. Mesopor. Materials 2012, 157, 50-55

CAU-5

[Zn2(NDC)2(1)]
1 = 3-azo-phenyl-4,4′-bipyridine

A. Modrow, D. Zargarani, R. Herges, N. Stock

The first porous MOF with photo-switchable linker molecules

Dalton Trans. 2011, 40, 4217-4222.

CAU-6

[Al13(OH)27(H2O)6(BDC-NH2)3Cl6(C3H7OH)6]

H. Reinsch, B. Marszałek, J. Wack, J. Senker, B. Gil,
N. Stock

A new Al-MOF based on an unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behavior

Chem. Commun., 2012, 48, 9486-9488.

CAU-7

[Bi(BTB)]

M. Feyand, E. Mugnaioli, F. Vermoortele, B. Bueken,
J. M. Dieterich, T. Reimer, U. Kolb, D. de Vos, N. Stock

Automated Diffraction Tomography for the Structure Elucidation of Twinned, Sub-micrometer Crystals of a Highly Porous, Catalytically Active
Bismuth–Metal–Organic Framework

Angew. Chem., 2012, 124, 10519-10522.

CAU-8

[Al(OH)(O2C-C6H4-CO-C6H4-CO2)]

H. Reinsch, M. Krüger, J. Marrot, N. Stock

First Keto-Functionalized Microporous Al-Based Metal–Organic Framework: [Al(OH)(O2C-C6H4-CO-C6H4-CO2)]

Inorg. Chem., 2013, 52, 1854-1859.

CAU-9

[Al2(OH)2(TCPB)],

[Sc2(OH)2(L)] L = PTCDA4–, TCPB4–, H2TCPP4–

M. Krüger, R. Siegel, A. Dreischarf, H. Reinsch, J. Senker, N. Stock

[Al2(OH)2(TCPB)] – An Al-MOF based on a tetratopic linker molecule

Micropor. Mesopor. Mater. 2015, 216, 27-35.

 

P. Rönfeldt, H. Reinsch, M. P. M. Poschmann, H. Terraschke, N. Stock

Scandium Metal–Organic Frameworks Containing Tetracarboxylate Linker Molecules: Synthesis, Structural Relationships, and Properties

Cryst. Growth Des., 2020, Accepted Article.

CAU‑10

[Al(OH)(m-BDC)]

H. Reinsch, M. A. van der Veen, B. Gil, B. Marszalek,
T. Verbiest, D. de Vos, N. Stock

Structures, Sorption Characteristics, and Nonlinear Optical Properties of a New Series of Highly Stable Aluminum MOF

Chem. Mater., 2012, 25, 17-26.

CAU-11

[Al(OH)(O2C-C6H4-SO2-C6H4-CO2)],

[Sc(OH)(SDBA)]

N. Reimer, H. Reinsch, A. K. Inge, N. Stock

New Al-MOFs Based on Sulfonyldibenzoate Ions: A Rare Example of Intralayer Porosity

Inorg. Chem., 2015, 54, 492-501.

 

P. Rönfeldt, H. Reinsch, N. Faßheber, H. Terraschke, N. Stock

Synthesis and Characterization of a Layered Scandium MOF Containing a Sulfone‐Functionalized V‐Shaped Linker Molecule

Eur. J. Inorg. Chem., 2020, 1147-1152.

CAU-12

[Al2(OH)2((O2C)2-C6H3-SO2-C6H3-(CO2)2)]

N. Reimer, H. Reinsch, A. K. Inge, N. Stock

New Al-MOFs Based on Sulfonyldibenzoate Ions: A Rare Example of Intralayer Porosity

Inorg. Chem., 2015, 54, 492-501.

CAU-13

[Al(OH)(1,4-CDC)]

F. Niekiel, M. Ackermann, P. Guerrier, A. Rothkirch,
N. Stock

Aluminum-1,4-cyclohexanedicarboxylates:
High-Throughput and Temperature-Dependent in Situ EDXRD Studies

Inorg. Chem., 2013, 52, 8699–8705.

CAU-14

[Cu3(PPT)(H2O)3]·11H2O

H6PPT = 2,4,6-tri-(phenylene-4-phosphonic acid)-s-triazine

N. Hermer, N. Stock

The new triazine-based porous copper phosphonate [Cu3(PPT)(H2O)3]·10H2O

Dalton Trans., 2015, 44, 3720-3723.

CAU-15

[Al2(OH)2(o-BDC)]

H. Reinsch, D. De Vos, N. Stock

Structure and Properties of
[Al4(OH)8(o-C6H4(CO2)2)2]·H2O, a Layered Aluminum Phthalate

Z. Anorg. Allg. Chem., 2013, 639, 2785-2789.

CAU-16

[Al(µ‑OH){AlPTC(µ‑OH)(H2O)}2]·2H2O

H3PTC = pyridine-2,4,6-tricarboxylic acid

M.T. Wharmby, M. Snoyek, T. Rhauderwiek, K. Ritter,
N. Stock

Group 13 Metal Carboxylates: Using Molecular Clusters As Hybrid Building Units in a MIL-53 Type Framework

Cryst. Growth Des., 2014, 14, 5310–5317.

CAU-17

[Bi(BTC)(H2O)]

A. K. Inge, M. Köppen, J. Su, M. Feyand, H. Xu, X. Zou,
M. O’Keeffe, N. Stock

Unprecedented Topological Complexity in a Metal–Organic Framework Constructed from Simple Building Units

J. Am. Chem. Soc. 2016, 138, 1970-1976.

CAU-18

[Ce4(H2TCPP)3(DMF)2(H2O)4]

T. Rhauderwiek, N. Heidenreich, H. Reinsch,
S. Øien-Ødegaard, K. A. Lomachenko, U. Rütt,
A. V. Sodatov, K. P. Lillerud, N. Stock

Co-Ligand Dependent Formation and Phase Transformation of Four Porphyrin-Based Cerium
Metal-Organic Frameworks

Cryst. Growth. Des., 2017, 17, 3462-3474.

CAU-19-X

[Ce3(H2TCPP)2(BA-X)(HBA-X/H2O)2]

X = H, 2Cl, 3Cl, 4Cl, 3CO2H, 4NH2, 4NO2

T. Rhauderwiek, N. Heidenreich, H. Reinsch,
S. Øien-Ødegaard, K. A. Lomachenko, U. Rütt,
A. V. Sodatov, K. P. Lillerud und N. Stock

Co-Ligand Dependent Formation and Phase Transformation of Four Porphyrin-Based Cerium
Metal-Organic Frameworks

Cryst. Growth. Des., 2017, 17, 3462-3474.

CAU-20

(CH3)2NH2)3[Al4(L1)3(L1•)3]·
((C6H2(OH)2(O)2), H2L1) and ((CH3)2NH2)3[Al4(L2)3(L2•)3]·

(C6Cl2(OH)2(O)2), H2L2),

S. Halis, A.K. Inge, N. Dehning, T. Weyrich, H. Reinsch,
N. Stock

Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum
Metal–Organic Frameworks

Inorg. Chem. 2016, 55, 7425-7431.

CAU-21

[Al(OH)(BPDC)], [Al(OH)(ODP)],

[Sc(OH)(OBA)]

M. Krüger, A.K. Inge, H. Reinsch, Y.-H. Li, M. Wahiduzzaman, C.-H. Lin, S.-L. Wang, G. Maurin, N. Stock

Polymorphous Al-MOFs based on V-shaped Linker molecules: Synthesis, Properties, and In-Situ investigation of their crystallization

Inorg. Chem. 2017, 56, 5851-5862.

 

P. Rönfeldt, E. S. Grape, A. K. Inge, D. V. Novikov, A. Khadiev, M. Etter, T. Rabe, J. Benecke, H. Terraschke, N. Stock

A Scandium MOF with an Unprecedented Inorganic Building Unit, Delimiting the Micropore Windows

Inorg. Chem., 2020, Accepted Article.

CAU-22

[Zr6(μ3-O)4(μ3-OH)4(μ-OH)2(OH)2(H2O)2(HCO2)2(PzDC)3]

H2PzDC = 2,5-Pyrazine-dicarboxylic acid

S. Waitschat, H. Reinsch und N. Stock

Water-based synthesis and characterisation of a new
Zr-MOF with a unique inorganic building unit

Chem. Commun., 2016, 52, 12698-12701.

CAU-23

[Al(OH)(TDC)]

D. Lenzen, J. Zhao, S. Ernst, M. Wahiduzzaman, A. K. Inge, D. Fröhlich, H. Xu, H. Bart, C. Janiak, S. Henninger,
G. Maurin, X. Zou, N. Stock

A metal–organic framework for efficient water-based ultra-low-temperature-driven cooling

Nat. Commun., 2019, 10, 3025.

CAU-24

[M6(μ3-O)4(μ3-OH)4(OH)4(H2O)4(TCPB)2]

M. Lammert, H. Reinsch, C. A. Murray, M. T. Wharmby,
H. Terraschke, N. Stock

Synthesis and structure of Zr(IV)- and Ce(IV)-based
CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Dalton Trans., 2016, 45, 18822.

CAU-25

[Zn2(H2PPB)(H2O)2]·xH2O

N. Hermer, H. Reinsch, P. Mayer und N. Stock

Synthesis and characterisation of the porous zinc phosphonate [Zn2(H2PPB)(H2O)2]·xH2O

CrystEngComm, 2016,18, 8147-8150.

CAU-26

[Zr6O4(OH)4(OAc)6(BDC)3]

S. Leubner, H. Zhao, N. Van Velthoven, M. Henrion,
H. Reinsch, D.E. De Vos, U. Kolb, N. Stock

Expanding the Variety of Zirconium-based Inorganic Building Units for Metal-organic Frameworks

Angew. Chem. Int.Ed., 2019, 58, 32, 10995-11000.

CAU-27

[Zr5O4(OH)4(OAc)4(BDC)2]

S. Leubner, H. Zhao, N. Van Velthoven, M. Henrion,
H. Reinsch, D.E. De Vos, U. Kolb, N. Stock

Expanding the Variety of Zirconium-based Inorganic Building Units for Metal-organic Frameworks

Angew. Chem. Int.Ed., 2019, 58, 32, 10995-11000.

CAU-28

[Zr6O4(OH)4(FDC)4(OH)4(H2O)4]

A.C. Dreischarf, M. Lammert, N. Stock, H. Reinsch

Green Synthesis of Zr-CAU-28: Structure and Properties of the first Zr-MOF based on 2,5-Furandicarboxylic Acid

Inorg. Chem., 2017, 56, 2270-2277.

CAU-29

[M(Ni-H6TPPP)(H2O)]
M = Mn, Co, Ni, Cd

T. Rhauderwiek, K. Wolkersdörfer, S. Øien-Ødegaard,
K. P. Lillerud, M. Wark und N. Stock

Crystalline and permanently porous porphyrin-based metal tetraphosphonates

Chem. Commun., 2017, 54, 389-392.

CAU-30

[M2(Ni-H2TPPP)(OH/F)2]·H2O

M = Zr, Hf

T. Rhauderwiek, H. Zhao, P. Hirschle, M. Döblinger,
B. Bueken, H. Reinsch, D. de Vos, S. Wuttke, U. Kolb,
N. Stock

Highly stable and porous porphyrin-based zirconium and hafnium phosphonates - electron crystallography as an important tool for structure elucidation

Chem. Sci., 2018, 9, 5467-5478.

CAU-31

[Bi2(H2TCPB)(TCPB)(H2O)2]

H4TCPB = 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene

M. Köppen, V. Meyer, J. Angström, A. K. Inge, N. Stock

Solvent-Dependent Formation of Three New Bi-Metal-Organic Frameworks Using a Tetracarboxylic Acid

Cryst. Growth. Des., 2018, 18, 4060-4067.

CAU-32

(NH2(CH3)2)[Bi(TCPB)(H2O)]

H4TCPB = 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene

M. Köppen, V. Meyer, J. Angström, A. K. Inge, N. Stock

Solvent-Dependent Formation of Three New Bi-Metal-Organic Frameworks Using a Tetracarboxylic Acid

Cryst. Growth. Des., 2018, 18, 4060-4067.

CAU-33

[Bi4(O)2(OH)2(H2TCPB)(TCPB)(H2O)2]

H4TCPB = 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene

M. Köppen, V. Meyer, J. Angström, A. K. Inge, N. Stock

Solvent-Dependent Formation of Three New Bi-Metal-Organic Frameworks Using a Tetracarboxylic Acid

Cryst. Growth. Des., 2018, 18, 4060-4067.

CAU-35

[Bi2(O)(OH)(TATB)]·H2O

M. Köppen, O. Beyer, U. Lüning, N. Stock

Synthesis, functionalisation and post-synthetic modification of bismuth metal-organic frameworks

Dalton Trans. , 2017, 46, 8658-8663.

CAU-36

[Co2(Ni‐H4TPPP)]⋅2 DABCO⋅6 H2O

B. Wang, T. Rhauderwiek, A.K. Inge, H. Xu, T. Yang,
Z. Huang, N. Stock, X. Zou

A Porous Cobalt Tetraphosphonate Metal-Organic Framework: Accurate Structure and Guest Molecule Location Determined by Continuous-Rotation Electron Diffraction

Chem. Eur. J., 2018, 24, 17429-17433.

CAU-38

[CeZr5(OH)4O4(PZDC)6]

H2PZDC = Pyrazoldicarboxylic acid

J. Jacobsen, H. Reinsch, and N. Stock

Systematic Investigations of the Transition between Framework Topologies in Ce/Zr-MOFs

Inorg. Chem., 2018, 57, 12820-12826.

CAU-39

[M12(μ3-O)8(μ3-OH)8(μ-OH)6(OH)6(H2O)6(APDC)6],

M = Zr, Hf

S: Waitschat, H. Reinsch, M. Arpacioglu, N. Stock

Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBUs

Cryst. Eng. Comm., 2018, 20, 5108-5111.

CAU-41

[Ce6(µ3-O)4(µ3-OH)4(SUC)4(OH)4(H2O)4]

H2SUC = Succinic acid

J. Jacobsen, B. Achenbach, H. Reinsch, S. Smolders, F.-D. Lange, G. Friedrichs, D. De Vos, N. Stock

The first water-based synthesis of Ce(IV)-MOFs with saturated chiral and achiral C4-dicarboxylate linkers

Dalton Trans., 2019, 48, 8433-8441.

CAU-42

Al und Ga HHTP

S. Leubner, V. E. G. Bengtsson, A. K. Inge, M. Wahiduzzaman, F. Steinke, A. Jaworski, H. Xu, S. Halis,
P. Rönfeldt, H. Reinsch, G. Maurin, X. Zou, N. Stock

Hexahyroxytriphenylene for the Synthesis of Group 13 MOFs - a New Inorganic Building Unit in a β-cristobalite Type Structure

Dalton. Trans., 2020, 49, 3088-3092.
CAU-43
[In(OH)(FeC12H8O4)]

J. Benecke, E. S. Grape, A. Fuß, S. Wöhlbrandt, T. A. Engesser, A. K. Inge, N. Stock, H. Reinsch

Polymorphous Indium Metal–Organic Frameworks Based on a Ferrocene Linker: Redox Activity, Porosity, and Structural Diversity

Inorg. Chem., 2020, 59, 14, 9969–9978.

CAU-44

[Ce6(µ3-O)4(µ3-OH)4(SUC)4(NO3)4(OH)2(H2O)2]

H2SUC = Succinic acid

J. Jacobsen, B. Achenbach, H. Reinsch, S. Smolders, F.-D. Lange, G. Friedrichs, D. De Vos, N. Stock

The first water-based synthesis of Ce(IV)-MOFs with saturated chiral and achiral C4-dicarboxylate linkers

Dalton Trans., 2019, 48, 8433-8441.
CAU-50 [Sc2(FcDC)3]

J. Benecke, E. S. Grape, T. A. Engesser, A. K. Inge, H. Reinsch

Observation of three different linker conformers in a scandium ferrocenedicarboxylate coordination polymer

Cryst. Eng. Comm., 2020, Advance Article.